Thursday, 30 December 2010

More wildfire, more bad air

From: Bettina Boxall, LA Times

Harvard University scientists are predicting some forms of air pollution could increase significantly across the West as more of the region's wildlands burn as a result of rising temperatures.
Smoke from wildfires contains two main kinds of carbon particles: black soot, or elemental carbon, and lighter-colored particles, called organic carbon aerosols, which are a mix of chemicals.
"In large quantities, downwind of fires, organic carbon aerosols are hazardous," said senior research fellow Jennifer Logan, who led a study examining rising wildfire rates and the impact on air quality. "The particles irritate lung tissue and the chemicals they carry are toxic. But even at low concentrations, these aerosols may be dangerous. We don't know. There is no known threshold where damage begins."
Article continues

Drax protesters found guilty of obstructing coal train

Climate change protesters face community service after judge rejects justification defence

Climate change protesters who ambushed and hijacked a power station coal train failed to convince a jury today that their actions were justified by the "imminent threat" of devastation from global warming.
The 22 men and women, including a senior university lecturer, teachers and film-makers, were convicted - after less than two hours of deliberation - of obstructing the service carrying 42,000 tonnes of coal to Drax in North Yorkshire last June.
Their hopes of repeating the "Kingsnorth Six" judgment last September, when activists who defaced a power station chimney were acquitted by a Kent jury, were dashed by a judge, who refused to admit arguments that the hijack was "necessary and proportionate to prevent the greater crime of carbon pollution".
Although he eventually allowed an unexpectedly large amount of evidence about climate change to be heard, Judge James Spencer refused to let expert witnesses such as Nasa scientist, Prof James Hansen, address the seven women and five men on the jury at Leeds crown court. In a pre-trial ruling he said that to do so would allow the protesters "to hijack the trial process as surely as they hijacked the coal train".
He did however compliment the group, who conducted their own defence, on making an "eloquent, sincere, moving and engaging" case to the court. After the verdicts, he said that sentencing in early September would definitely not include jail terms, but was likely to be community service.
The 22, plus a further five protesters who earlier pleaded guilty and two who are ill but expected to submit guilty pleas in due course, will however face hefty financial penalties. The crown is applying for both its costs and £36,000 compensation for cleaning up coal shovelled on to the tracks during a 16-hour standoff with police.
After the verdict, one of the 22, Dr Louise Hemmerman, 31, said: "The judge declared from day one that climate change was irrelevant to the trial, despite the fact that it was the sole reason for doing what we did."
Another of the group, Jonathan Stevenson, 27, who works for a development charity, said: "This won't be the last case where climate protesters are in court for taking peaceful direct action, and while some judges may think climate change is irrelevant, they won't be able to hold back the tide forever."
Stevenson asked the judge after the verdicts if an order banning the defendants from power stations would apply more widely, to include roads. Judge Spencer replied with a smile: "I would steer clear of demonstrations, all of you, until this case is completely over. Try to find some other activities to do on your holidays."
Hansen, head of Nasa's Goddard Institute for Space Studies, whom the defendants had intended to call to the stand to speak about the science of climate change, said: "Civil resistance is not an easy path, but given abdication of responsibility by the government, it is an essential path."
Hansen was arrested last week for his part in a protest over mountaintop coalmining in West Virginia. He has previously said that direct action is necessary because the democratic process is not bringing about policy change fast enough.
The chief crown prosecutor for North Yorkshire, Rob Turnbull, said: "While the CPS [crown prosecution service] respects the rights of individuals to lawfully protest, it takes a serious view of criminal activity which targets those carrying out lawful activities." He defended Judge Spencer's pre-trial ruling on the grounds that no one was in such immediate danger from global warning that hijacking a coal train was "proportionate".
"The judge said that if the power station contributed to global warming, and all that entailed, it was for the government to attend to and not the protesters. He also said that no reasonable jury could conclude that the crime these defendants allegedly committed was either reasonable or proportionate when there were democratic processes available in this country for political change."
The 22 were acquitted of actually stopping the train, after evidence that no one knew which of them had donned fake railwaymen's uniforms and used red flags to bring it to a halt. The ambush stopped the train right on a bridge over the river Aire, whose girders gave protesters the means to clamber up and use 15 shovels to start unloading coal.
Passenger and freight services in the area were disrupted for two days, but Drax generated power normally throughout.
Those convicted were: Theo Bard, 24, Amy Clancy, 24, Brian Farelly, 32, Grainne Gannon, 26, Bryn Hoskins, 24, Jasmin Karalis, 25, Ellen Potts, 33, Bertie Russell, 24, Alison Stratford,26, Jonathan Stevenson, 27 and Felix Wight, all of London, Melanie Evans,25, Matthew Fawcette, 34, Robin Gillett, 23, Kristina Jones 22, Oliver Rodker, 40 and Thomas Spencer,23, all of Manchester, Paul Chatterton, 36, and Louise Hemmerman, 31, of Leeds, Melanie Evans, 25, of Stockport, Paul Morozzo, 42, of Hebden Bridge, Christopher Ward, 38, of Newport Pagnell and Elizabeth Whelan of Glasgow.
The five who pleaded guilty earlier were: Theo Brown, 22 and Clemmie James, 24, of London, Malcolm Carroll, 53, of Stafford, Thomas Johnstone, 25, of Liverpool and Paul Mellett, 29, of Colerne, Wiltshire. The two have indicated they will plead guilty when well are Caroline Williams, 25, of London and Sam Martingell, 24, of Leeds.

Sunday, 12 December 2010

World is running out of oil--then what?

I think it is no secret now, when I tell you that the world is running out of oil. (See Hubbert's peak.) Up until now, most of our oil has been used to make energy (or as fuels). This has got to stop because the day is coming when oil will be more valuable than energy, and will be needed for other uses. (Should I mention global warming?) That brings up a new and timely idea.



If we think of using oil to make energy as a reaction:



Oil --> energy.



We should remind ourselves that the reaction is reversible, at least in principle:



Energy --> oil



There is an inefficiency involved in going either way. The existence of this reversible reaction has the effect of placing a link between the cost of energy and the cost of oil. Some examples:



1) The cost of oil can not be substantially lower than the cost of equivalent energy from other sources (allowing for inefficiency), otherwise energy production will shift to use of more oil. (Which just supposes that economics has more sway than common sense.)



2) The cost of oil can not be substantially higher than the cost of equivalent energy from other sources (allowing for inefficiency), in the long run, because man's inventiveness will allow oil to be made from energy.



The question then follows as to whether there are or can be practical means for making oil from energy.



We may say that we live in an exciting time, when the world has to face a transition from the "industrial age" when we have powered everything with fossil fuels. The daily advance of news on this, this summer, is quite surprising. The underlying question is, what will replace oil? Wind turbines, etc., make electricity, not oil. The question hasn't been very important until now, when we can see that we really are going to run out. There are maybe three answers to the question--



1) Biomass to oil, fuel, etc. An example is NREL's research on using the Fischer-Tropsch (or F-T) process to convert trash to oil--not the best approach. The direct conversion with pressure and heat is better (sorry, don't have the reference, now in pilot plant operation). There are many others, including my favorites: growing biomass at sea for conversion to methane, and producing "biodiesel" from low-value crop materials.



2) The darling of industry, converting coal (or natural gas, oil shale, etc.) to liquid fuels. This is already in use in one two-step process: "coal gasification" to synthesis gas, then coversion to long-chain hydrocarbons with the F-T process. This produces a very good-quality diesel fuel, or about anything else you want. Pretty rough on the environment, so only half a solution.



3) Efficient conversion of electricity or other high-quality energy directly to hydrocarbons. Most of the good alternate energy approaches produce electricity. Okay, I will list the best of these: wind, tide /wave, PV, and solar-thermal. A unique exception, a dish solar concentrator, can also produce high-quality heat (10,000 suns) at the focus.



Number three is exactly what I was talking about. It is the only one that makes sense but doesn't rely on photosynthesis. Notice that I have excluded hydrogen from consideration, as a replacement for oil and other liquid fuels. I know further that hydrogen can be made from electricity, and in turn can be used to make hydrocarbons, by the F-T process. This looks way too expensive and inefficient to get very far, in my judgement.



I was searching around on the internet last night, looking for new ideas on making synthetic oil or hydrocarbons--Ideas that would fall within #3. I found nothing! This topic, producing hydrocarbons from electricity or heat directly, is of great importance for the future of man. Though it may be a little early yet, this will be a major problem soon. When we (the world) turn our attention to it, solutions will quickly emerge. I see two paths:



1) Use of heat. Two reactions at high temperature have been mentioned in the past:



H2O --> HO + H --> H2 + O2

CO2 --> CO + O --> CO + O2



Removing the oxygen, the products together are "synthesis gas," which can be used to make alcohols or long-chain hydrocarbons by the F-T process. Or, either of the gases singly, with water or CO2, can be used to the same end.



There are surely many other known processes that I am unaware of.



2) Use of electricity to make hydrocarbons directly. This seems to be a largely unexplored field, having been at an economic disadvantage for the last century. Here, two approaches come to mind: plasma chemistry, driven by electrical power. A subset of this are the thermal processes mentioned in 1).



A second approach is well known, but not worked on currently, I think-- that is organic electrochemistry for making fuels. In principle, electrochemical reactions carried out in cells can make hydrocarbons and other organic materials. A few industrial processes already exist that do this sort of thing.



Michael Faraday reported an experiment that should be a point of beginning for research. He passed an electric current through a solution containing carbonate ion, and discovered that organic compounds were formed. (Formic acid or formaldehyde?)



I hope I have shed some warm light on Hubbert's peak.



Ernie Rogers